I wasn't sure whether to rec this under Smut or Firsts: Bareback (http://archiveofourown.org/works/4019038") (comics AU) by Sineala. I ended up going with Firsts because so much of what I like about this one is how it's about it being their first time, and figuring that out... complicated by it being a first-time in human-centaur relations. (Yup, this is that fic!) It's very sweet, occasionally (wondefully) awkward, and an all-over great first time fic.
On a less porny note, I'm also going to rec Four Times Steve Said I Love You and One Time Tony Said It First (http://archiveofourown.org/works/811441) by Nightwalker and the accompanying art (http://archiveofourown.org/works/1153647) by Leperu. This hits a number of firsts over a period of time, and it lives up to its 'schmoop' tag in the best of ways. Mmmmm, yes.
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On a less porny note, I'm also going to rec Four Times Steve Said I Love You and One Time Tony Said It First (http://archiveofourown.org/works/811441) by Nightwalker and the accompanying art (http://archiveofourown.org/works/1153647) by Leperu. This hits a number of firsts over a period of time, and it lives up to its 'schmoop' tag in the best of ways. Mmmmm, yes.